Something I have long pondered and will soon find out as I return to C-41 developing soon. I've done it with D-76 but it wasn't a long time enough test. When I suggested freezing in the B&W forum a few years ago everyone ran screaming from the room, so to speak.
But why not? These are just chemicals, organic and not, they are not veggies with cellular structures that change when frozen. Obviously, when frozen no chemical actions or degrading can be taking place.
I'm not sure if you mean the powdered developer - which is, AFAIK, stable - or mixed, liquid chemicals.