Hit the test button on the pocket wizard that's connected to the lens a bunch of times and see if it works reliably. You can also try plugging the strobe straight into the lens and see how that works. The results will tell you if it's a problem with the radio triggers or not.
If the above indicates the pocket wizards are working reliably, the next easiest thing would probably be to try another sync cable between the lens and PW.
The sync circuit on the RB67 is built into the lens, not the camera, so we can rule out the camera. If the shutter trips, the camera has done all it needs to do to fire the strobe.
One of my RB67 lenses won't trigger the strobe unless I jam the PC cord in there pretty good, but it's usually pretty reliable once it's in there. If the above test indicates that your pocket wizards are working reliably and the cable is OK, then you might want to see about cleaning the PC port on the lens . Beyond that, might need to have a pro look at it.