There is a wealth of information about Pyrocat and the density from the stain in this article by Sandy King:
http://unblinkingeye.com/Articles/PCat/pcat.html
The blue channel is recommended for measuring the silver plus stain density.
It is quite possible to use a scanner as a densitometer. The absorbance, or density, is defined as:
D = -log(I/Io)
where I is the intensity of light passing through the material, and Io is the intensity without the absorbing material. For some scanners and software, it is possible to get a linear signal such that the pixel value is proportional to the light intensity. This usually requires turning off auto exposure and any non-linear curve adjustment. I have gotten good results using a Minolta Scan Dual III (with the Minolta software) and with an Epson V500, using VueScan. I haven't figured out how to defeat the autoexposure on a Nikon scanner, however.
To get absolute absorbance values, you will probably need to have a calibration standard, such as a step wedge from Stouffer:
http://www.stouffer.net/TransPage.htm
The other thing that is helpful is the program ImageJ:
http://rsbweb.nih.gov/ij/
This is an excellent open-source image analysis program, and it makes it easy to measure the average values for a patch of pixels.
I can provide more details on using a scanner as a densitometer, though I don't have the information at hand right now.
David