• Welcome to Photrio!
    Registration is fast and free. Join today to unlock search, see fewer ads, and access all forum features.
    Click here to sign up

Precipitate in Sulfte solution

pdeeh

Member
Allowing Ads
Joined
Jun 8, 2012
Messages
4,770
Location
UK
Format
Multi Format
I've made up a solution of Sodium sulfite (anhydrous) at 30g/l ... it seemed fully dissolved and perfectly clear when I decanted from the mixing vessel to the storage bottle, but within a few hours a soft white precipitate formed at the bottom. I used water from an ordinary kitchen filter jug at room temperature. The sulfite was purchased from a reputable supplier of photographic chemicals.

I can easily run the solution through a filter it of course, but why should this have happened?

Would using Sodium hexametaphosphate (or similar) in the water, or deionised water, help avoid the formation of precipitate?
 

Gerald C Koch

Member
Allowing Ads
Joined
Jul 12, 2010
Messages
8,131
Location
Southern USA
Format
Multi Format
If you used tap water then the white precipitate is probably calcium sulfite. Next time use distilled or de-ionized water.
 
Last edited by a moderator:
OP
OP

pdeeh

Member
Allowing Ads
Joined
Jun 8, 2012
Messages
4,770
Location
UK
Format
Multi Format
Thank you Gerald