When I began experimenting with alternative photographic processes I started doing gum bichromate prints because of the pictorial look, it is inexpensive and you can use a great variety of papers. Most people do gum printing with layers of different colors but I only did monochrome prints with layers of the same color (black). All of these processes use bichromates in gum arabic as the sensitizer which hardens selectively according to the amount of light received and mainly differ in their binding material and the pigments. In bromoil, a gelatin silver bromide is bleached and the silver is replaced with ink. Gumoil is a positive transparent image that is contact printed to an unpigmented gum arabic surface that has been sensitized with potassium bichromate (see link below to Anna Ostanina's site, she also has a number of youtube videos demonstrating the process)
The main caveat of these processes is the use of bichromates (dichromates) and that is the reason I don't do gum printing anymore. It is a nasty chemical, it has been banned in the EU and it should be banned everywhere. If you go that path, you should collect the gum-developing run off into a plastic tank, convert it to trivalent adding sodium thiosulfate (spent fixer). It is now trivalent chromium compound that is much safer but you can go further and make it safer for disposal with more treatment. And by disposal I mean taking it to a hazardous waste disposal center. Be aware that some pigments are also toxic. You need to wear a particulate respirator and if you don't have one it could be difficult to get now because of Covid.
It seems that there is an alternative to dichromates using something called "Diazo sensitizer" but I didn't try it.
https://www.alternativephotography.com/gum-diazo-printing-v1-4/
There is also a photographer/printer who claims to have a safe alternative to dichromates. She calls it "ecoGumoil".
https://annaostanina.com/ecogumoil
There are a couple of books that go over pigmented processes:
https://www.amazon.com/Photographic...tographic+possibilities&qid=1619973758&sr=8-2
https://www.amazon.com/Dimensions-P...sion+in+photo+processes&qid=1619973784&sr=8-1