I do not think that this is a matter of adjustment (which is done simply enough under the camera: there are two ratchet screws close together), as such adjustment simply makes either the first or second curtain more or less tensed. Here, there is a problem with the two curtains not meeting closely enough, which leads me to believe that one curtain's two apron strings, holding its curtain to its round post, is too short, or glued too far around that post so that its reach does not conform with complete and necessary overlap.
That is rather tricky to correct, as it means you must remove the four front screws holding the mount area, un-glue those specific apron strings, then re-glue at the proper point. If you do remove this mount be especially careful to not let those four tiny, light brass spacers under the mount get into the body.)
That said, there MIGHT be a simple tensioning of a curtain to make. Cock the shutter half way so that the slit is as you show in the picture. Then gently move each curtain separately 'BACK' to the neutral position to feel if one of the curtains is not sufficiently tensioned. If the springiness is too weak, that curtain's ratchet screw needs to be slightly tightened.
By the way, I consider these pre-Spotmatic versions of Pentax to be the most aesthetic of all SLRs. - David Lyga