I've tried using Dektol (idea was from a magazine article) to do film and results were downright awful!!! Other folks have had success with it, but it's not something I'm really itching to try again.
In general, your negs will come out too contrasty and grainy when using a paper dev on film. However, I've read where Dektol 1+9 can be useful. Again, haven't tried it.
Film dev on paper can work if the strenght is right. I accidently mixed my Rodinol wrong one night and instead of throwing it away, I made prints with it. It worked, but nothing special. I think in the chemistry section here, there is a recipe for Rodinol warm-tone paper dev.
In general, film dev is meant for film, paper dev for paper. However, there is a bit of artist in each of us and with a bit of time and energy, who knows what you can come up with