It probably does not matter.
Back in the early days of digital negatives, MK had significantly more density in the UV than PK. These days the difference is small, but MK is still a bit more dense than PK.
If you are making your own curves, pick one and stick with it.
If you are using a curve generated by someone else, they should tell you which ink to use.
I read somewhere years ago when I first got into using digital negatives that mk had a hard time adhering to some OH materials. Because of that, I've stuck with Pk. I'm currently running a 3800 and P400, all black inkset, and one yellow.
I have used both on Pictorico (SC-P600 printer) and didn't noticed any big difference. Both are very effective UV blocking inks. However, the curves applied to the DN were slightly different for PK an MK.
By the way, I couldn't make QuadToneRIP work with SC-P600. It apparently support the printer but somehow fails on the run. However, the "Advanced B&W " mode of the printer, using only black and gray inks, is very predictable - sort of QuadToneRIP preset, I'd say.
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