Orwo

mohmad khatab

Member
Joined
Sep 8, 2012
Messages
1,228
Location
Egypt
Format
35mm
What is this brother?
I was expecting that in this link I would see the successful experiences of positive slides and the magnificence of the beautiful images, but I was surprised that the link is a frustrating discussion of black and gray spots problems, and at the end of the discussion it did not reach radical solutions to these problems and no knowledge Its causes ,,
- This is a bond that frustrated me, man - I am sad.
 

Lachlan Young

Member
Joined
Dec 2, 2005
Messages
4,942
Location
Glasgow
Format
Multi Format

Old, less well hardened emulsions are potentially vulnerable to pinholes from developers that use carbonate as their alkali when they hit an acid stop.
 

JPD

Member
Joined
Mar 24, 2007
Messages
2,155
Location
Sweden
Format
Medium Format
Old, less well hardened emulsions are potentially vulnerable to pinholes from developers that use carbonate as their alkali when they hit an acid stop.

I did the mistake to develop Efke R50 in a developer with carbonate and then an acid stop. Carbon dioxide formed in the emulsion, causing the negatives to be grey and full of tiny bubbles. Totally unusable. I should have used plain water as stop and a neutral or alkali fixer.
 
Joined
Jul 28, 2016
Messages
2,726
Location
India
Format
Multi Format
Old, less well hardened emulsions are potentially vulnerable to pinholes from developers that use carbonate as their alkali when they hit an acid stop.

That's true. However, in the specific case of Orwo UN54 I did experiment a bit with developers that had carbonate in them, IIRC Crawley's FX1 and didn't get the spots. It seemed that catechol with carbonate was necessary for the spots to appear. I discussed the issue with PE and he said it could be an emulsion issue but can't confirm it without further tests. Fortunately for me, the film worked fine with Adox MQ Borax and reversed ok with Kalogen.
 

Dennis S

Subscriber
Joined
Mar 16, 2008
Messages
1,761
Location
Vancouver B.C.
Format
Multi Format
I was just using water stop and then used TF-5 fixer and I tried different things such as Kodak stop but the pinholes continued so I stopped using that combination. Years ago I remember using Pyrocat HD 1-1-200 on the film with never any problems and really liked the way the negatives that it did turn out as it was great for wet prints. Thinking of getting fresh UN54 from Germany but shipping seems to be a real problem lately.
 

Klaus_H

Subscriber
Joined
Apr 18, 2006
Messages
115
Location
Lower Saxony
Format
Medium Format
I am using UN54 with PMK at 64 ASA since 10 years . It works very well.
N74 fits perfect to the ADOX ATOMAL 49 developer.
 
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