sulfation..
Before you use one, mixed, or unmixed, in the case of the liquid ones, just pour them into another jug/tray/ etc before use, then sniff the empty container and look for yellow residue. If you find it, the fixer has had the sulfur come out of solution. I would stay clear of this stuff, and dump the lot on the idle flower bed out in the garden- it will love the ammonia. Once the sufation starts in a liquid fix I have never seen it stop.
On the dry fixes, mix them up. There may be a few yellow sulfur bits that form, but in this case I don't worry about them, because they are the result of individual crystals deteriorating, vs the whole lot being on the verge of dumping its sulfur. Others may hold different views, and dump any fixer showing sulfation.
Otherwise, do the usual how long does it take for the leader to claer, then double it to fix the film.
I just mixed up a dry package of 5l worth of agfacolor 60 fix from a late 70's bleach fix kit that the amm ferric edta was missing from. It still works fine, and fixes very quickly.