I am using old Technidol that came in the foil packets. It works as well as ever. I am also running out of the stuff and I will probably have to try TD-3.
I am not sure about Technidol using Phenidone - my experience with Phenidone is that it goes bad in front of my eyes, as opposed to Technidol's 20+ year life. Maybe Technidol uses some Glycol or other, or as Graig states there is some magic preservative in it. I have never had good results with POTA, but I never bothered finding out why.
My understanding is that POTA was formulated at Kodak for developing photographs of Atom Bomb explosions. I believe a panchromatic-cousin-of-microfilm was also developed for Los Alamos; this A-Bomb film was then sold as Solar Flare Patrol film, which in turn became Technical Pan. Thus explaining Tech Pan's sensitivity to the red hydrogen line and it's popularity with astronomers.
If I had my druthers the last films left standing would be Kodachrome 25, Ektar 25 and Technical Pan. It seems I am not in any sort of majority when it comes to druthers.