I know it's a really good camera, but the camera that surprised me the most was my F100..now hear me out:
I had an FE and an N80 before that and never really got good images out of them. It seemed like everything looked muddy and my negs were thin. It really turned me off of film because the images looked so bad. It seemed like it was always a crap shoot when I used the N80. I sold it, shot digital for years, then got my hands on an gripped F100 and SB26 for $75 (it was covered in Coca Cola). Cleaned it up and found out that aside from the soda it was in great shape. Shot of a few rolls of that, and I don't know if it was the light or the metering, but the images looked GREAT. Punchy, clean, detailed, totally different than my N80. Since than, I don't know if it's confidence, or something else that's psychological, but that F100 is what really surprised me with what film could do and really helped me be confident in taking my business into a film workflow.