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Markings on tintypes?

Kulwulton River in Flood

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Kulwulton River in Flood

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-chrille-

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Having problems with markings on wet plate tintypes. It looks like oil on water. It is still seen after varnishing. What is the cause of these defects?

I only get this on tintypes not on ambrotypes. And my process is exactly the same for both types.

IMG_2470.jpeg
 

koraks

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I think it has something to do with the paint layer on the black plates you're using. You could try applying a coating on top of that (perhaps just black paint, or a clear varnish), then pour collodion over that. See if the same iridescence still emerges.
 
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-chrille-

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Thanks! Will try coating on some of the plates and see if that helps.
 

Ian C

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It is the phenomenon of Thin Film Interference. This is often seen when a thin layer of gasoline lies atop water, such as when a drop of gasoline drips onto calm water while fueling an outboard motor on a small boat alongside a dock.

It’s also seen just after a light rain when the thinner components of motor oil float on wet asphalt.

It doesn’t require oil. Many thin transparent materials will produce this effect.

https://www.google.com/search?q=thi...MuNLgH5QXCBwkwLjIuMC4zLjLIB1c&sclient=gws-wiz

It is the basis of antireflection coatings applied to filters and lenses.

https://en.wikipedia.org/wiki/Thin-film_interference
 
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-chrille-

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Good explanation.

I also think about Newton rings but that might be the same physical properties?
 

koraks

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The optics behind Newton rings are similar, the cause and solution tend to be different. In a very general sense, you could group them all under 'interference caused in the interface of two layers' - but that doesn't get you very far in solving the issue, I suppose.
 
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