IB Photochemistry
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- Oct 8, 2006
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Color Separation negatives of color transparencies are primarily of interest to those making Dye TransferTM or dye imbibition transfer color prints, but can also be used for printing transparencies on RA-4 materials, color pigment processes, archiving images, and more. They can even be of interest to those interested in making black and white internegatives of color transparencies and other fields areas such as making color corrected duplicates and internegatives on chromogenic films.
While there are a number of procedures for making color separations in the published literature, none were used in the industry to commercially produce dye transfers, as those were inadequate. Methods used to make color separations by professional dye transfer labs were regarded as trade secrets and jealousy and selfishly guarded, but I have found many of the systems used in the industry were remarkably similar. Since there may be some interest in techniques once used to make dye transfers commercially, I think I should post an internal manual I have obtained used by Frog Prince & Company inc. to make the color separation negatives they used to make prints. The manual is from 1985 and used Kodak Super XX pan film. This was used until they bought a Versamat processor to make separations using Kodak Separation Negative films. I have attached the copy of the shop manual below. I think it would be of value to the community to openly discuss these techniques for making commercial quality separations and Kodak DT prints, as this is largely an area void of historic documentation.
I'm sure there will be some questions about this so please ask and I will try to answer. I don't have the lab's specific aimpoints for making matrices, and some information may be specific to their setup. The main DT operator at Frog Prince, Tom Rankin has been deceased for more than 25 years. This came from someone affiliated with the lab who has allowed me to publish it here.
In the manual there is a kind of mask they call a “mid-range” mask. Its really the same as a long scale highlight mask and produced in the same way. Basically its a low contrast highlight mask developed in HC-110 Dil. E, with low density (<0.60 DU) and is made by exposing though the principle masks, just like making the separation negatives with the transparency. The “mid-range” is used as a post mask while exposing the matrix with the separation negative, and does not receive more than 60% of the full exposure time as the separation negative does.
The “mid-range” has effect on the midtone and highlight areas. From my research this is also called a Long Scale Highlight mask or Long Range Highlight mask. Its function is to maintain spacial modulation in the principle mask; this expands the range of the mask and eliminates halation flair. This is necessary because you don't want halation flair from the principle masks in your images. Many books speak of using alternative films for making principle masks with an antihalation layer (without diffusion), however this was not used commercially because the diffusion of the mask improves spacial modulation of the separations. This kind of mask was made with every set at Frog Prince.
The highlight mask is made from Kodalith Pan (some labs used Agfa Litex P911P instead) and developed in D-19 1:2 for 2½ min. It is used as a post mask and receives at least 50% of the exposure that the separation negatives does. Highlight masks are needed with color transparencies because the product of the matrix toe (and dye system), and toe on the transparency have an effect of reducing contrast in the highlights, producing flat highlights. The highlight mask has the effect of raising the contrast of the highlights to preserve highlight detail.
There is a highlight pre-mask in the manual. I don't know if they used this very often. I also don't know if they added this mask back with the principle mask to to restore its curve to a more flat and linear curve. Otherwise highlights and upper midtones would have a crossover.
Usually a specular mask is made with the highlight mask and is used as a post mask when exposing the matrices. It would be less than 25% of the total exposure time with the separation negatives. The manual stops on page 29, but its possible some additional pages are missing. I think most labs used at least one of these masks with a set. Specular highlight detail can be lost due to light scattering in the various intermediate films used.
Frog Prince did make a Shadow masks with the set. Between 2-3 were made and were used as post masks to reduce contrast of the separation negatives, opening up the shadows slightly or even for color correction, by placing on the other color records. They are made by contact printing through and exposing through the blue filter, using the separation negative with a sheet of Kodak Pan Masking film, processed in HC-110 1:23 for 2.00 min (20 C). Sometimes these are called Contrast Reducing Masks (CRM), I think. If a high separation gamma is used such as 0.75-0.90 all three will be needed. Gamma of the separations could be controlled by controlling the percentage of time the mask was exposed with the separation negatives.
In the case of high contrast separation gamma, perhaps >=0.90 a highlight mask of the negative possibly called a “black mask” or “shadow highlight” can be made, and then contact printed with the separation negative to the pan masking film. This makes a contrast reducing mid tone mask with the effect of keeping shadow contrast high. I think the use of a “black mask” to make the main contrast mask was used more with Separation film since this operates better at 0.90 gamma and above, so the effect of shadow contrast gain will be higher.
Color correction on the transparency dyes itself can be performed using a set of isolation masks or chroma correction masks. They are made by first making a gamma 1 positive of all three separation negatives, using Kodak Commercial film 4127 or Gravure positive film. The separation positive is then contact printed with a different separation negative, onto a high contrast film such as Kodalith Ortho or Technical pan film. For Kodalith film, the mask is processed in D-11 straight for 2 min (20 C). Up to six of these masks can be made. They are exposed with the separation negatives for a fraction of the total matrix exposure time.
These isolator masks work by removing the unwanted absorption sidebands of the transparency, resulting in better color reproduction and saturation. Its used as a type of hold back mask when exposing the matrices, that isn't a 'negative' or a 'positive' image, rather it represents a pure color record that was blocked by the dye sideband absorption. Its also possible to use this technique in reverse, to de-isolate a given color, by printing the separation positive with different separation negative onto the matrix, if the transparency has an over correction for a certain color.
Area masks were made on litho film to keep a border on the image. Various litho film masks can be used as dodge or burn masks. Some masks were spotted by hand with crocein scarlet for dodging certain areas. From what people tell me, Frog Prince also dodged and burned matrices by hand, using adjustable wires on an XY axis jig to maintain color registration.
There is another type of important mask that was used infrequently, sometimes called a shadow contrast enhancement mask. This raises the contrast of the shoulder portion of the characteristic curve. Between 1-3 of these can be made. I think Frog Prince only made 1 of these if it was needed. There are two ways to make this type of mask. One is to over expose a piece of litho film with the transparency to get only the shoulder part of the curve, the other method (and probably more controllable) is to make the shadow enhancement mask off of the separation interpositives. Unfortunately I don't know how Frog made this mask. I think it may have been applied if there was an area on the transparency that was underexposed.
Here is an example of how these separations and masks might be exposed onto Kodak matrix film. Again I don't have their aim-points for exposing matrices, so I'm using some other information I have here.
Cyan Matrix:
exp.______________________________Time (s)
1 Separation + HL + CRM_____________12.5
2 Separation + HL + Red Isolator_______12.5
3 Separation + HL + Specular__________15.0
4 Separation + MID__________________10.0
Magenta Matrix
exp._______________________________Time (s)
1 Separation + HL + CRM______________15.0
2 Separation + HL + Green Isolator_______10.0
3 Separation + HL + Specular___________15.0
4 Separation + MID + Red Isolator_______10.0
Yellow Matrix
exp.___________________________________Time (s)
1 Separation + HL + CRM_________________ 0.0 – (1.3?)
2 Separation + HL + Blue Isolator___________25.0
3 Separation + HL + Specular______________15.0
4 Separation + MID______________________10.0
5 Green Sep. + Green HL + Blue positive_____10.0
While there are a number of procedures for making color separations in the published literature, none were used in the industry to commercially produce dye transfers, as those were inadequate. Methods used to make color separations by professional dye transfer labs were regarded as trade secrets and jealousy and selfishly guarded, but I have found many of the systems used in the industry were remarkably similar. Since there may be some interest in techniques once used to make dye transfers commercially, I think I should post an internal manual I have obtained used by Frog Prince & Company inc. to make the color separation negatives they used to make prints. The manual is from 1985 and used Kodak Super XX pan film. This was used until they bought a Versamat processor to make separations using Kodak Separation Negative films. I have attached the copy of the shop manual below. I think it would be of value to the community to openly discuss these techniques for making commercial quality separations and Kodak DT prints, as this is largely an area void of historic documentation.
I'm sure there will be some questions about this so please ask and I will try to answer. I don't have the lab's specific aimpoints for making matrices, and some information may be specific to their setup. The main DT operator at Frog Prince, Tom Rankin has been deceased for more than 25 years. This came from someone affiliated with the lab who has allowed me to publish it here.
In the manual there is a kind of mask they call a “mid-range” mask. Its really the same as a long scale highlight mask and produced in the same way. Basically its a low contrast highlight mask developed in HC-110 Dil. E, with low density (<0.60 DU) and is made by exposing though the principle masks, just like making the separation negatives with the transparency. The “mid-range” is used as a post mask while exposing the matrix with the separation negative, and does not receive more than 60% of the full exposure time as the separation negative does.
The “mid-range” has effect on the midtone and highlight areas. From my research this is also called a Long Scale Highlight mask or Long Range Highlight mask. Its function is to maintain spacial modulation in the principle mask; this expands the range of the mask and eliminates halation flair. This is necessary because you don't want halation flair from the principle masks in your images. Many books speak of using alternative films for making principle masks with an antihalation layer (without diffusion), however this was not used commercially because the diffusion of the mask improves spacial modulation of the separations. This kind of mask was made with every set at Frog Prince.
The highlight mask is made from Kodalith Pan (some labs used Agfa Litex P911P instead) and developed in D-19 1:2 for 2½ min. It is used as a post mask and receives at least 50% of the exposure that the separation negatives does. Highlight masks are needed with color transparencies because the product of the matrix toe (and dye system), and toe on the transparency have an effect of reducing contrast in the highlights, producing flat highlights. The highlight mask has the effect of raising the contrast of the highlights to preserve highlight detail.
There is a highlight pre-mask in the manual. I don't know if they used this very often. I also don't know if they added this mask back with the principle mask to to restore its curve to a more flat and linear curve. Otherwise highlights and upper midtones would have a crossover.
Usually a specular mask is made with the highlight mask and is used as a post mask when exposing the matrices. It would be less than 25% of the total exposure time with the separation negatives. The manual stops on page 29, but its possible some additional pages are missing. I think most labs used at least one of these masks with a set. Specular highlight detail can be lost due to light scattering in the various intermediate films used.
Frog Prince did make a Shadow masks with the set. Between 2-3 were made and were used as post masks to reduce contrast of the separation negatives, opening up the shadows slightly or even for color correction, by placing on the other color records. They are made by contact printing through and exposing through the blue filter, using the separation negative with a sheet of Kodak Pan Masking film, processed in HC-110 1:23 for 2.00 min (20 C). Sometimes these are called Contrast Reducing Masks (CRM), I think. If a high separation gamma is used such as 0.75-0.90 all three will be needed. Gamma of the separations could be controlled by controlling the percentage of time the mask was exposed with the separation negatives.
In the case of high contrast separation gamma, perhaps >=0.90 a highlight mask of the negative possibly called a “black mask” or “shadow highlight” can be made, and then contact printed with the separation negative to the pan masking film. This makes a contrast reducing mid tone mask with the effect of keeping shadow contrast high. I think the use of a “black mask” to make the main contrast mask was used more with Separation film since this operates better at 0.90 gamma and above, so the effect of shadow contrast gain will be higher.
Color correction on the transparency dyes itself can be performed using a set of isolation masks or chroma correction masks. They are made by first making a gamma 1 positive of all three separation negatives, using Kodak Commercial film 4127 or Gravure positive film. The separation positive is then contact printed with a different separation negative, onto a high contrast film such as Kodalith Ortho or Technical pan film. For Kodalith film, the mask is processed in D-11 straight for 2 min (20 C). Up to six of these masks can be made. They are exposed with the separation negatives for a fraction of the total matrix exposure time.
These isolator masks work by removing the unwanted absorption sidebands of the transparency, resulting in better color reproduction and saturation. Its used as a type of hold back mask when exposing the matrices, that isn't a 'negative' or a 'positive' image, rather it represents a pure color record that was blocked by the dye sideband absorption. Its also possible to use this technique in reverse, to de-isolate a given color, by printing the separation positive with different separation negative onto the matrix, if the transparency has an over correction for a certain color.
Area masks were made on litho film to keep a border on the image. Various litho film masks can be used as dodge or burn masks. Some masks were spotted by hand with crocein scarlet for dodging certain areas. From what people tell me, Frog Prince also dodged and burned matrices by hand, using adjustable wires on an XY axis jig to maintain color registration.
There is another type of important mask that was used infrequently, sometimes called a shadow contrast enhancement mask. This raises the contrast of the shoulder portion of the characteristic curve. Between 1-3 of these can be made. I think Frog Prince only made 1 of these if it was needed. There are two ways to make this type of mask. One is to over expose a piece of litho film with the transparency to get only the shoulder part of the curve, the other method (and probably more controllable) is to make the shadow enhancement mask off of the separation interpositives. Unfortunately I don't know how Frog made this mask. I think it may have been applied if there was an area on the transparency that was underexposed.
Here is an example of how these separations and masks might be exposed onto Kodak matrix film. Again I don't have their aim-points for exposing matrices, so I'm using some other information I have here.
Cyan Matrix:
exp.______________________________Time (s)
1 Separation + HL + CRM_____________12.5
2 Separation + HL + Red Isolator_______12.5
3 Separation + HL + Specular__________15.0
4 Separation + MID__________________10.0
Magenta Matrix
exp._______________________________Time (s)
1 Separation + HL + CRM______________15.0
2 Separation + HL + Green Isolator_______10.0
3 Separation + HL + Specular___________15.0
4 Separation + MID + Red Isolator_______10.0
Yellow Matrix
exp.___________________________________Time (s)
1 Separation + HL + CRM_________________ 0.0 – (1.3?)
2 Separation + HL + Blue Isolator___________25.0
3 Separation + HL + Specular______________15.0
4 Separation + MID______________________10.0
5 Green Sep. + Green HL + Blue positive_____10.0