Thanks for the help everyone. Some more data.... I've seen this with two rolls of Portra 400 I processed myself a couple of months apart with a different mixing of chemicals (same concentrate, just two batches of working solution). I've also seen this with a roll of Reala I shot back in July that was processed commercially at a decent lab (it was at a fairly good local camera store, not at a mini lab). I'm attaching a few examples of this.
portra-1 is the example from August that I processed. portra-2 is the example from the other day that I processed. reala is the example from July that was commercially processed. Only one of these photos is any good.
-jbl
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I've seen the same in Ektar scans when underexposed. The shadows shift to purple. Didn't matter if I developed or a lab developed. I started shooting to make sure the shadows had enough exposure and I don't really see it often any more. Ektar can handle quite a bit of overexposure. This does bring up a subject I posted on quite a while back about the Ektar data sheet giving exposure settings for ISO 50 film, not it's box speed of 100. If you look at the recommended exposure settings for given lighting in the datasheet it's the same as Velvia 50. Things that make you go "Hmmmmmmmm".......
I just checked some of my Portra 400 scans and I see the same purple shift in dark, underexposed areas. It becomes more noticable when you boost the lower end of the tone curve to lighten the dark areas. I don't think it has anything to do with your processing, it's more a trait of the film when scanned. I can't say if the same thing would happen when using traditional printing techniques.
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