Longevity of unopened Ektacolor RT/LU and Tetenal Monoline colour dev

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lantau

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I thought I won't have to care about RA4 chemistry for a while. However, it seems I was procrastinating for a little too long. My last period of RA4 printing was from late 2018 to early 2019. I kept pushing the switch back from b/w to RA4.

I had drained and cleaned my Nova slot processor and today I finally started to mix my Kodak Ektacolor chemicals. They were stored in my darkroom, located in a relatives basement. The part B bottles of the developer set didn't look good. I can't remember how dark they looked when I first used it. I had two of four 5L sets left in the box, all remaining containers unopened. And indeed, mixing resulted in a black solution, not the golden colour, which it should have. I am a little suspicious of the blix, but I hope it'll be ok.

I'm wondering, for how long others have been keeping unopened Ektacolor chemicals around? Is two to three years too long?

This set I received from Ag Photographic in the UK in spring 2018. I also bought a second set a year later, because Brexit would soon cut me off from Ag Photographic, the only supplier to consumers. This is stored in my own basement, and after opening the box, I saw that it is gone as well.

Storage was fairly cool. The basement room in my place will reach 20°C, maybe 22°, in hot Summers and is much cooler in winter. My positive dark room is in a relatives boiler room. But with the door open it will have around 22°C during a hot Summer. Up to 25°C when I close the door and do dark room work at some weekends. And the bottom of the shelf at an outside wall, where the chemicals sit should be cooler. In winter I measured chemicals at as low as 12°C.

I check a previously unopened C41 Flexicolor box in my basement and it shows the expected colour of the part with the CD4, btw. Also in the dark room I had kept RA4 tank solution for the whole time, stored in a PET 5L container filled to a third. Unfortunately I just had disposed of it at this years final special waste collection by the county. I thought it's so old, lets make 'fresh' solution.

Now I need new chemicals and available options are not that great. I don't want one of those RA4-kits of dev+blix tank solutions. The Nova pretty much requires a replenishment regime. Fuji makes some great odorless stuff, and there is a single shop, which is selling some of the pro line to private customers. But these are too large and too expensive for me. They make 2x20L, 2x50L or 1x100L.

I never considered Tetenal before, but I finally ordered some of their Monoline developer: 4x 10L. I chose the one with the highest replenishment rate of 160mL/m², which is the original standard rate. The highest possible replenishment rate helps with the low throughput of a private darkroom. That is why my next C41 chems will be Fuji odorless dev with 60mL replenishment per film. That set also makes 2x5L, which is more convenient than the 2x10L Flexicolour.

Monoline chems are a single solution, which requires only dilution. I do have an empty 10L container, already. Made from very thick PE, a very wide lid and looks like a milk can, including handle. Sold by a lab supply company for chemical storage. I use a 5L version for Flexicolour tank solution and Xtol.

Does anyone have experience with the shelf live of these unopened Monoline chemicals?

Apparently it didn't help to have the Kodak product split in three components.And colour tanks solution in large, airtight containers seem to keep for months and even years. So maybe the Monoline stuff turns out to be the way to go. It's basically a 10x concentrate. I'd be very worried about their Monoline blix, though.

The incoming package will provide me with 40L of replenisher from four bottles of concentrate. That is a bit much, depending on the shelf life of the unopened bottles. If anyone in Germany or the EU wants some, I'd offer the other bottles at cost plus shipping. That is €32,46 for each bottle (yielding 10L replenisher). Should be a 2kg parcel. Germany with DHL would be €5 and EU countries €14, I believe. I also ordered starter and could fill a small bottle to go with it. I'll be using the chemicals at 35°C, meaning I won't be able to say anything about room temp processing. The next thing will be that my Kodak Endura paper is two years old, now, as well...
 
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Tom Kershaw

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Does anyone have experience with the shelf live of these unopened Monoline chemicals?

I have a nearly full bottle of the Tetenal Monoline product you're referring to - I haven't printed RA-4 for a while and had run out of the other bottles. In the past I have used the Kodak Ektacolor line without a problem. Generally speaking I'd expect a mono concentrate to last less well than a 3-part.
 

DREW WILEY

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I haven't used Tetenal in a long time. With Kodak Ra/Rt and generic clones, the small bottle Part B developer component goes bad long before the other bottles. Wish I could buy that by itself. 2 years unopened I did fine .... but 3 years? ... Just gotta see when I finally get to uncorking it. But I'm not especially optimistic. I ran out of color paper around the beginning of Summer and am just getting around to ordering some more.
 

halfaman

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I found Ektacolor RT/LU developer packaging too simple, no seals and some bottles are not even full. I would not put my money in that chemistry if not going to use it in short term.

I don't have experience with Tetenal but I do have with Fuji Hunt Enviroprint MP-60 monoconponent developer that I buy in 4x10 liters batches (four bottles to do with each one 10 liters of replenishment or 15 liters of working solution). Good packaging and excellent shelf life, using it already for a couple of years and in the second bottle right now without any problem.
 
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lantau

lantau

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I have a nearly full bottle of the Tetenal Monoline product you're referring to - I haven't printed RA-4 for a while and had run out of the other bottles. In the past I have used the Kodak Ektacolor line without a problem. Generally speaking I'd expect a mono concentrate to last less well than a 3-part.

I would have expected the same. The Ektacolor bottle containing CD3 is very small. Being highly concentrated (if it is) can be beneficial, as shown by Rodinal, but doesn't have to be. High concentration also means high reaction rate if it is capable of chewing itself up.

Considering the results I think it does an oligomerisation (a 'junior' polymerisation). Of course every chemist knows that any reaction does that and results in dark, smelly tar. The art of chemistry is to extract the little bit of the intended target contained in it...

I haven't used Tetenal in a long time. With Kodak Ra/Rt and generic clones, the small bottle Part B developer component goes bad long before the other bottles. Wish I could buy that by itself. 2 years unopened I did fine .... but 3 years? ... Just gotta see when I finally get to uncorking it. But I'm not especially optimistic. I ran out of color paper around the beginning of Summer and am just getting around to ordering some more.

Fuji and Tetenal are selling one line of colour devs in individual parts A,B,C. But it is 20L concentrate, or more, of each part. But anyway, I agree. If only I could buy Part B.

As Murphy will have it I may have to buy paper next, if the Kodak paper didn't keep. That would be such a shame, though. I was so happy to be able to get it. I've looked up which papers Fuji is selling. In the European market the generic paper names are CA, CA Supreme, CA Supreme HD and CA DP-II in what seems to be in order of increasing quality grade.

I found Ektacolor RT/LU developer packaging too simple, no seals and some bottles are not even full. I would not put my money in that chemistry if not going to use it in short term.

I don't have experience with Tetenal but I do have with Fuji Hunt Enviroprint MP-60 monoconponent developer that I buy in 4x10 liters batches (four bottles to do with each one 10 liters of replenishment or 15 liters of working solution). Good packaging and excellent shelf life, using it already for a couple of years and in the second bottle right now without any problem.

Yes, the colour dev bottles have no aluminium foil seals. The blix bottles do, however. And they are 4x larger.

Am I understanding right, your Fuji monoconcentrates have been keeping for several years, already? Sounds promising. My chosen Tetenal chemistry has a much higher replenishment rate than your MP-60 (160ml/m² vs 60mL/m²). Even then that is enough for 250m² of paper. Minus the replenisher from which I'll make tank solution. That is 10 rolls of 30.5cm wide paper. I guesstimate 10 years of printing?
 

halfaman

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Ten years could be a lot even it is well packaged, but I think 2-3 years should be just fine. Take into consideration that usually there is no manufacturing date on photochemistry packaging and some shops use it to sell old stock remmants.
 
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lantau

lantau

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Ten years could be a lot even it is well packaged, but I think 2-3 years should be just fine. Take into consideration that usually there is no manufacturing date on photochemistry packaging and some shops use it to sell old stock remmants.

I don't expect it to last for ten years. But I estimate that would be the theoretical capacity at my usage. But maybe I'm wrong. I might still try to offload two bottles.

In any case. I ordered the box (4x 1L of concentrate) at Nordfoto and it arrived two days later, in time for the following weekend. Works like a charm and I like the single concentrate. I didn't dilute the whole bottle but take out only what I need. It is ethyleneglycol based. Probably not water free, but maybe the syrup will keep well. As usual I use Butane as a protective gas.

I do have a feeling that I received some old stock. The bottles seem to have the labels of the old Tetenal company. No mention of Tetenal 1847. At the end of last year I received a box of C41 teststrips two months from expiration. So I do wonder a bit about this. I buy from that shop on a regular basis and am generally very happy with them.

My Kodak blix is still working as far as I can judge. That means I have plenty of that. Another 25L of replenisher waiting to be mixed up, and I'm not worried about it going bad.

My Kodak paper, on the other hand. The unexposed border is definitely fogged, now. There might be a little yellow in it. My feeling is that it is more like a warm shifted colour balance, than a yellow cast. It is quite a contrast when directly comparing the white borders to those of prints from two years ago. But looking at it under 5500K light my brain sees white. And the pictures look nice. I guess I'm having a rare warm tone paper, which you couldn't buy anywhere.

So again, I like the prints so far. But my visual cortex is a consumer model and works on full auto white balance. I have no absolute vision. But I can see a difference very well. I also printed APS film from my consumer point 'n shoot days for the first time. Good thing about ISO100 indoors with flash is that the colour balance doesn't change from frame to frame.

Today I received Fuji CA Type DPII. Again, I ordered from Nordfoto. Because no one else is selling rolls to consumers. And this time I received, most likely, fresh product. Nordfoto didn't ship it themselves, but it came directly from Fujifilm in the Netherlands.

Once I can compare side by side I'll see how bad my Kodak roll really is. Or maybe I'll hate the Fuji Paper. :smile:
 

halfaman

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Today I received Fuji CA Type DPII. Again, I ordered from Nordfoto. Because no one else is selling rolls to consumers. And this time I received, most likely, fresh product. Nordfoto didn't ship it themselves, but it came directly from Fujifilm in the Netherlands.

Once I can compare side by side I'll see how bad my Kodak roll really is. Or maybe I'll hate the Fuji Paper. :smile:

Fuji CA DPII is my favourite paper among all I tried but it is a matter of taste.

I find weird that you didn't find any other store selling RA4 paper in rolls, it is a Spanish web but check this out...
Papel Químico - Grupo Universal (fotogrupouniversal.com)
 
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lantau

lantau

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Fuji CA DPII is my favourite paper among all I tried but it is a matter of taste.

I find weird that you didn't find any other store selling RA4 paper in rolls, it is a Spanish web but check this out...
Papel Químico - Grupo Universal (fotogrupouniversal.com)

I have to admit, I didn't look as far as Spain. I wonder how much the shipping would be. Or if they, too, would drop ship directly through and from Fuji in the Netherlands.

One roll is €15 less than what I paid, that's quite a bit. The shop is Spanish, only, which makes it more difficult. I just ordered in a shop that is Dutch, only. I absolutely don't understand spoken Dutch, but I could handle finding what I needed there and create an account. They had Pro400H (120) back in stock for €10 a roll. Less than Portra 400. :smile:

But thanks for the tip. I have to keep my eyes open. There seem to be more and more interesting shops for film photography all over Europe. And thanks to the EU it is often quite easy to use them. I ordered some camera scanning tools from Finland a short while ago. They had a nominal shipping charge and it was here in a day by express.
 
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