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lith bleach formulas and some experiments

Mark Fisher

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I was doing some experiments over the weekend to dry to reduce the warm tone in some lith prints. I bleached them back in CuSO4/sulfuric acid bleach and found that when I redeveloped in lith, it came up nearly immediately and the tones were much closer to neutral.....like a warmtone conventional print. That made me think about the effect of the rehalogenating agent in the bleach. Most call for Potassium bromide, but can NaCl also be used as a direct substitute? I'd think the resulting redeveloped prints would be a bit warmer than they might otherwise. I'll give it a try in a few days if no one speaks up.

Thanks -- Mark
 

grahamp

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I can't answer to what will happen on a lith-treated print, but I do have a reference to a Sodium Chloride/Potassium Ferricyanide bleach as giving warmer tones. This is for sepia toning, nominally. 6.6g Sodium Chloride to 35g Potassium Ferricyanide made up to 1l.


(Creative Elements, Ephraums E., Amphoto 1993)
 
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Mark Fisher

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That seems to make sense to me......definitely worth a try. Why use expensive KBr when I can use table salt!
 

Rudeofus

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Note that 30 g/l Sodium Chloride are supposedly used in Microdol X as silver solvent! While AgCl is poorly soluble (but still a lot more soluble than AgBr or AgI), there are quite soluble Silver Chloride complexes which will become more of an issue as you increase Chloride level.