Hi Ivenhoe,
That is minor fogging (note the red streaking), caused by stray light reaching the film. You probably have a small light leak in your camera or (less likely) the film cassette, but the latter seems less likely because this is frame 23. It's probably a problem with the camera; check the camera back is fully light-proofed, the light seals are in good condition (they can decay with age) and that the back closes properly, especially along the bottom.
Good luck,
kevs.