It generates sodium metaborate tetrahydrate which is Kodalk ,you are correct. They are of course partly ionized in solution.At some stage long ago, I made a note of Kodak advice that in place of 10g Kodalk (sodium metaborate) one could use 1.5g sodium hydroxide plus 7g borax. So this is what I have been using in bath B of Barry Thornton's two-bath developer (so 1.8g NaOH plus 8.4g borax in 1 litre of solution), and it seems to work very nicely.
What I'm not clear about is whether this mixture generates sodium metaborate chemically in solution, or whether it is simply a substitute. Can anyone explain the chemistry to me, please?
About the deterioration of solid NaOH in storage...my wife suggested making it into a molar solution in water as soon as it was delivered, which is what I did. Then one has to do the maths, but you can easily work out how much to add to substitute for the pure solid form.
Dry storage in a tightly-sealed container should keep the hydroxide stable for a long time. The usual trouble is how the chemicals were stored prior to purchase (a thick HDPE bank with a seal is a great barrier, but a heat-sealed PE bag offers less "protection").About the deterioration of solid NaOH in storage...my wife suggested making it into a molar solution in water as soon as it was delivered, which is what I did. Then one has to do the maths, but you can easily work out how much to add to substitute for the pure solid form.
What also helps (perhaps) - I usually get my NaOH as drain cleaner pellets. The pellets don't easily absorb aerial moisture - and they're of course packaged in a properly sealed plastic container.Dry storage in a tightly-sealed container should keep the hydroxide stable for a long time.
What also helps (perhaps) - I usually get my NaOH as drain cleaner pellets. The pellets don't easily absorb aerial moisture - and they're of course packaged in a properly sealed plastic container.
I've seen people ridicule the use of drain cleaner NaOH for photography purposes. It's OK - they probably never tried. The only drawback is that the pellets don't dissolve as easily as flakes or powder. The advantage, though, is that this also makes them much more safe to handle!
Pellets are what I use. I wonder if the process described by @Nikola Dulgiarov will work with pellets as well or does it strictly need powdered NaOH?
Raghu, if your pellets are the same grade as the ones on the website, I think you'll have a hard time with the dry preparation. Dissolve the hydroxide in the water and after it cools down to 30-40C, add it to the borax with strong manual stirring.
Raghu, if your pellets are the same grade as the ones on the website, I think you'll have a hard time with the dry preparation. Dissolve the hydroxide in the water and after it cools down to 30-40C, add it to the borax with strong manual stirring.
Nikola, I'll try keeping it in the refrigerator and see.
This worked. I was afraid that after taking it out of the refrigerator, the solid might thaw into slurry but it seems to hold up. I just need to break it into smaller pieces.
Breaking it up is a hassle, but I'd put the mass into a strong plastic bag and apply a hammer enthusiastically.
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