I personally prefer to proportionately mix only enough chemistry for a given daily session. PET bottles vary in quality. Some of those sold in camera stores are quite thin and allow oxygen to penetrate. Then there are serious lab grade ones. You want them full, or else use an inert gas to displace air. Developer has A,B,and C components, with the lesser quantity B being by far the worst in terms of dicey storage life. I really don't know how long the full unopened,unmixed concentrates last. Perhaps two or three years after manufacture, depending. But I really don't trust mixed developer for more than a few days, and even that long would worry me with respect to the best possible results.