Yes. Lovely film. As its name implies, more vivid than its Portra NC ("natural color") cousin, but still with good skin tones. I use it when I need a bit more color saturation than I get from my standard Fujicolor 160S or 400H films (both of which I to be between Kodak's NC and VC lines in terms of color saturation, and a bit "cooler"). Very nice sharpness and fine grain.
None of these are as saturated as Velvia transparency film, which I've used but little. If you have experience with transparency films, someone here more knowledgable than I about those could chime in with a comparison.
I think, setting aside the varibles with different developers as I only use 2, the use of films has a lot to do with personal tastes and the choice of lenses. I do prefer the 400H, 160S, Provia slides. Most of my lenses are the older German types for example a few Leicas, Rolleiflex TLR (Tessar, Planar and Xenotar - 75/3.5), a few Solinar, Apotar, Color-Skopar and Tessars (in both 135 and 120 6x6 formats). Other films may be more at home when using other lenses. But when it comes to grains, most of Kodak and Fuji's are rather good.
Also, it may just be me, I have always found Velvia 100 to be slightly under-rated, that is, I found it exposing better at 50-64 instead. Anyone has the same observation?