I have a few. A lot of them work fine if you understand their limitations. You will lose lens speed, you will enhance any lens aberrations and you will increase the chance of flare. Since you just effectively doubled the focal length of your lens you also increased the chance of camera shake and/or subject motion. This last one is probably the single biggest misunderstood factor when using tele-converters. Your reduced aperture requires longer shutter speeds at the same time that you doubled the focal length. You now have a totally different lens to work with.
If you have an excellent lens to start with, you will have a very good lens with the doubler. As mentioned, stop down the lens, mount the camera to a tripod, use a lens hood and go for it.
Always understand your limitations. Remember, an excellent composition using a doubler trumps line pairs per millimeter every time.
EDIT - Just like everything else, practice, practice, practice. People buy a doubler, carry it around in their bag for weeks, finally see a chance to use it one day. So they open the box for only the 2nd time since it arrived via post, unwrap it, slap it on their 70-200/f3.5-5.6, lean it against a tree and take a few shots. They crank the zoom to 200mm where it is now f5.6. They leave it there because they have heard that the lens aperture is now f/11. With the Velvia 50 film they are using their shutter speed is now about 1/30 seconds, if they are lucky. Their zoom wasn't terribly great at 200mm until stopped down to about f/8 or f/11 in the first place and now they think they can use it wide open.
They get home and find soft and/or blurred photographs. If they had taken those pictures with just the zoom, came how and doubled the magnification on their monitor those photos would have looked about the same. Instead they immediately conclude that all doublers are terrible and throw it in a drawer. Six years later they take it out of the drawer and sell it on Ebay, still like new, still in the box.
Of course none of us have ever bought that doubler or repeated that poor guy's mistakes...