Yep, if you want to minimize toxicity, you want Caffenol for negatives, and cyanotype or salted paper for prints. Cyano chemistry is fairly benign, possibly more so than silver nitrate. Can't get around fixer, though, and you need Ware's 2019 "simple" cyanotype to be able to control contrast without getting (carcinogenic and environmentally nasty) potassium dichromate involved. FWIW, thiosulfate is pretty easy on the environment; if you one-shot it, it can even go into municipal water treatment in home-lab quantities without trouble. Or just put it on your roses...