Hi David,
Not sure if or how one can do this with standard QTR techniques, which I have not studied in depth. However, QTR has the option of controlling each ink with its own curve (same syntax as the Gray Curve). I have written an Excel spreadsheet that generates these curves (actually have evolved this over several years). I think others also do this to generate custom QTR profiles. I'm working on making this user-friendly enough to publish as a shareware item that can be used to generate quick and accurate profiles for any process. Still ironing out the details...
If you want to see what is going on inside your QTR profiles (on Mac) you can open the .quad file as a text file and look at the individual ink profiles. I guess one could figure out a routine for editing that, but I have not looked into it.
Best, Ben