With Damp Rid etc (calcium chloride canisters), there is no worry with respect to those chemicals sublimating into the surrounding atmosphere. They're highly hydroscopic. But you want to be darn sure none of it gets on your hands or gets spilled (dry or wet) or
even a drop of it gets on any of your gear or shelving, because it's very difficult to completely remove, and turns any surface into a moisture magnet. Terrible for leather. So when canisters need recharging with fresh crystals, or disposal, you want to be careful. But that solution is energy passive and highly effective in confined spaces like camera or gun safes, or drawers and closet shelves. But silica gel has to be baked out quite often under similar circumstances.