Using multi spot metering of EOS3 is very easy. You set camera to spot metering mode. Next, you aim lens toward scene you want to measure its light and press FEL button, release button, aim lens toward next scene press FEL again, and like that up to 8 times. Camera make all calculations and you have 16 seconds after last pressing of FEL button to make your photograph. If you not make your photograph in 16 seconds, measuring is canceled and you have to repeat it again. Please, have in mind you don't have to make all 8measurings, 8 is maximum, you can measure 2 or 5...
When to use multispot metering? Well, let say you want to make portrait of person under umbrella in summer. So, you have bright light of Sun, and you have face of person in shade. And let say you are not sure how much exposure compensation to give to average metering, because if you make error, either persons face will be too dark or too bright, or scene surrouning that person would be too bright, that is washed out and you really want to have well exposed face with details and well exposed scene with details.
So, you will use multi spot metring to measure face (its brightest and darkest parts), brightest and darkest part od the scene, and/or other important parts of the whole scene. Please, have in mind that, as with other meters, you have to have basic metering knowledge, and to implement it. For example you can not use automatically spot metering of white and black person. White will be too dark and black will be too light if you use automatically what meter show. So, you have to know basics of metering. Altought, atleast for EOS3 and its spot metering, when I used it exposure was allways "perfect" so no need to lots of thinking there
Have in mind that film can handle around 5 stops contrast range. So, if you darkest and lightest parts of scene are into 5 stops, you can develop your film "normally" and you will have good exposed photo.
If contrast range is more than 5 stops, you probably will lose details either in brightest or darkest parts of the scene. If that is case, you probably would need to use zone system of exposure/developing.
Hope this helps. Good luck.