If you shoot old structures, you can't actually always count on them being straight and plumb.
I've drawn gridlines on my groundglass so I don't have to rely on the edge of the frame.
Make sure the tripod is level, so that if you pan with the head in the neutral position (you may also want to mark the neutral positions on your tripod head and camera for quicker setup), the camera stays level. I start with the camera level, checking the rail (if I'm using a monorail camera) and the front and rear standards along both axes.
I try to correct first with front rise (or rear fall, if you have it). This produces a more natural result than with rear tilt alone, which only corrects verticals in one plane, like tilting the enlarging easel or using PhotoShop's "perspective correction" tool. If I run out of front rise and still have more image circle, I might add some indirect front rise if necessary by tilting the camera up and applying front and rear forward tilt in parallel to compensate.