Assuming that you are using the UV light for something like platinum printing - I'm not an engineer or anyone who is an expert on UV light, but from what I've been told, UV light that your images are sensitive to does not go around corners or reflect off surfaces - it has to be direct exposure. Case in point - when you stand in the shade out doors, is it possible to get sun burned from the sun reflecting off other surfaces? Given that, it shouldn't matter what the interior of your light box is. If you use a white or reflective surface coating, it may look brighter to your eye, but your image may not be sensitive to that extra light (different wavelength). Maybe there are some more experienced people here who can either confirm my understanding or correct it with more accurate information.
(As you probably already know) Best UV reflector is Aluminum. You'll gain some speed if you line inside the box with aluminum panels...
Well, the reason why I cautioned against bare metal is that the reflections can be irregular. If you take the time to make a really good half cylinder or something, then yes, maybe it's a good idea, but otherwise I think the reflected light will be uneven.
Of course, if the reflective surface is a long way away, then ... inverse square law... it won't matter.
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