i was told by someone in the biz yesterday
that the buffer is added because the materials used to make the papers
are slightly acidic sometimes.
That is very often the case. Many makers refer to a paper as "acid-free", but often what it means in reality is it is actually slightly acidic with alkali buffers added during manufacturing to get back to a neutral pH, or there abouts.
From researching and looking at paper specifications over the last few years I don't think there are that many watercolour papers that have no buffers of any sort in them these days, and this concurs with the views of the staff at my local paper supplier who must be fed up with me asking for lots of samples of different paper each time I visit.
Based on my experience, if I paper needs an acid pre-soak try and find an alternative, it is just an added step and results are usually not as good as using a compatible paper from the start. An acid-pre-soak can also damage a paper's sizing too so you have to be careful, especially if it is just surface sized, so results can vary a lot between papers.