Glycine Storage Glycine developers

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Wisner

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Just thought I would throw this out there. Like many, I use glycine in several of my film and paper developer formulas. The issue is, glycine does go bad very quickly as compared to other reducing agents. To make a long story short, I got very ill, could not go to my darkroom for over a year. I did not want my glycine to go bad as I had about 200 grams on the shelf.

When I purchase glycine from Photographers Formulary, I pay the extra and have the chemical placed in a dark brown glass bottles, that helps the storage issue. Longer storage has been achieved by placing the glass bottle in the refrigerator, darkroom fridge, not food fridge. As I was so sick ,I needed longer storage so placed the dark brown in well sealed glass bottles in the bottom of my deep freezer. As an added protection I placed the bottle in a ZipLock style plastic bag.

It is now some 18 months later and I am some better, went to my frozen glycine and warmed it up overnight. To my surprise the color of the glycine was almost the same color as when purchased. I Mixed up some GSD-10 and my version of Ansco's 130 paper developer. Both of the developers worked as expected.

To sum this up, for longer storage of glycine, try freezing in well sealed glass bottles. It has certainly worked for me. Now, after mixing the required chemistries, I place the glass bottle back in the freezer ratter than siting on my shelf. Always warm the bottle up overnight or condensation of moisture will happen in the bottle, nothing good will happen with moisture in a Glycine bottle.
 

Wayne

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It will last a lot longer than a year in the freezer. I've used it at least several years old, and I currently have some in the freezer thats from 2006. It still looks quite good. It will still work even when it turns brown, thought it may stain, but this is still nearly white after 14 years.
 
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Wisner

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Wow, 2006, like I said, wish I knew that a very long time ago, much glycin wasted.
 

Wayne

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Wow, 2006, like I said, wish I knew that a very long time ago, much glycin wasted.

And its in a half-used bottle. I won't be testing it until Polywarmtone comes back, but it looks great. I've used much worse, chocolatey glycin.
 

grainyvision

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I can also confirm even without much care (half empty plastic bottle in a ziplock), keeping glycin frozen will massively slow it's degredation. I keep a big container of my "stock pile" in my freezer and a small ~50g bottle in my fridge so it's easier to access and I don't need to thaw the entire amount every time I need to mix something

edit: Note, from personal experience I don't have to worry about condensation (yay high altitude desert climate), but do not try to mix glycin from frozen unless you have a lot of patience. It gets clumpy and a lot harder to mix into solution
 
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