I've not had a problem with mine yet, so can't really comment on what to look for, aside from the obvious (fungus, damage, etc.).
On the backs, make sure the exposure setting and compensation dials move easily when the lock is pulled back. If you load film (or just backing paper to test), make sure the shutter will NOT fire with the dark-slide in. This would usually be an issue with the back (not the camera), and is not a deal-breaker, but it can be hard to remember to remove the dark-slide if the shutter will fire. (I have one back that does this, but that is it's only problem.)
Changing backs can be a bit confusing. If you cock the shutter, then swap backs, I think you will still need to wind again before it will fire. If I remember correctly, you'll have to use the multi-exposure lever to wind once (or waste a frame) after swapping backs.