Normally one would buy sodium sulfite with a specific formula in mind. As mentioned above, it's an ingredient. Not an additive. It's a part of the recipe of literally hundreds of photographic processing formulas, primarily as a preservative. But there are other more subtle reasons for its use as well.
The only sulfite-only formula I can think of at the moment would be a 2% solution used as a poor man's hypo clearing agent.
If you have purchased some of this chemical in error, consider becoming an APUG Subscriber (which allows access to the APUG Classified advertisements, as well as the photo galleries) and post it as a For Sale item. You will likely recover most of your money from someone with a working darkroom. And possibly break even on the APUG subscription price, which would be an equally good deal.
Ken