That is in fact a PC (Prontor-Compur) flash sync connector. And yes, old mechanical shutters are completely safe to use with modern electronic flashes.
Yes, there was a period when electronic flashes had high voltage (in some cases, up to 600 V) present on the sync terminals, and those are capable of damaging unprotected electronic sync shutters (like those in some of the late generation film cameras and early DSLRs), but even among those, there were only a couple obscure models that I'm aware of having damaged the metal mechanical contacts in a mechanical leaf shutter.