Film emulsions evolutionary development, and how that translated for the photographer and printer

OP
OP
Joined
Jan 7, 2020
Messages
44
Location
Melbourne, Australia
Format
Multi Format
Oh yes Fuji's development in colour was a process decades in the making
Alas, even Fuji made a kodachrome process film
 

MattKing

Moderator
Moderator
Joined
Apr 24, 2005
Messages
53,892
Location
Delta, BC Canada
Format
Medium Format
Oh yes Fuji's development in colour was a process decades in the making

Alas, even Fuji made a kodachrome process film

Fuji did make a film with a process that had some similarities to the process employed in Kodachrome, but it wasn't the film that made Kodachrome so successful, it was the combination of the film and the processing infrastructure.
And it was only movie film - particularly home movie film - that made that infrastructure economically viable.
Much of the impetus behind many of the improvements in film technology came from the requirements and desires of the film processing industry. And Kodak made a lot of its profit from serving that industries needs.
 
OP
OP
Joined
Jan 7, 2020
Messages
44
Location
Melbourne, Australia
Format
Multi Format
Now this is fascinating. And a belt sander at that. I imagine the coating head is the most precise aspect of the operation, as would the perfectly flat surface contacting the base side of the film where the coater meets.
It makes me wonder how hard a coating head would be to make or have made. precision is the name of the game.
the other factor is the environment you have around the coater, temp and humidity controlled.
he's rather fortunate to have access to old film formulas and the equipment to make it.
It doesn't surprise me at all that for b&w the only product evolution's came in the form of computer based production refinement.
The last big product change in still films was in 2008-11 with Ektar and the new Portra 160, 400. Portra 800 is referred to be based off Vision 2 and not overhauled then.
Yes, and "ektar" was reintroduced with kodaks plans to axe E-6 all together which they eventually did as we all know.
Desirable for some but certainly not all. people are under the impression that film always looked weird, with colour crossovers and just general expired behaviours. But that simply isn't the case and it's a shame so many take on this view.
It is interesting how the new color journey for Harman, Lucky, Adox and Orwo/Inovis are to leap into C41 Color as far good as possible.
C41 is certainly the hardest to coat and produce. But it is the largest market, so they've willingly jumped into the deep end. I was hoping for more improvements in Pheonix II, looks like we've got a long road ahead there.
About contemporary B&W, would point classic films as Fomapan and Adox CHS 100. If quite a bit of them is mostly older 50-70s tech.
Foma's greatest downfall is QC. their 100 speed emulsion is actually fairly decent. Have yet to try Adox
 

Peter Schrager

Subscriber
Joined
Jul 19, 2004
Messages
4,233
Location
fairfield co
Format
Large Format
 
Joined
Jan 28, 2023
Messages
1,391
Location
Wilammette Valley, Oregon
Format
35mm RF

I’ve used CHS 100 II quite a bit and I would recommend it to anyone who is pining over Panatomic-X. It has a lot to offer and definitely has classic film type traits.
 

Prest_400

Member
Joined
Jan 1, 2009
Messages
1,487
Location
Sweden
Format
Med. Format RF
Check out the smarter every day Kodak video series where they go through manufacturing and R&D. It is quite impressive and really interesting to see what I read described here through PE's contribution.
Also, there was some coating discussions in the Efke threads as well as one with the 1958 Kodak manufacturing video. Back then
IIRC the modern coating methods are using curtain coating which is described in the Smarter Every day video.

Some relevant or interesting things I found searching for references to the above:

The Efke thread is very interesting, regarding the older methods of manufacturing! Sadly they closed in 2012 as the factory fell apart and before the current resurgence of film. Understanding that their technology was rather simple, ADOX were able to reproduce it with their modern equipment. Top of mind I am not sure, but ADOX has Ilford's former Swiss machinery and maybe as well some Agfa Leverkusen coater?
For Polywarmtone, they did need to acquire Forte's emulsion equipment, otherwise that would not be a product to reproduce. Quite fascinating and interesting. Recommend you to delve into their website where they posted in the process of building their current factory, and some info is also shared in their partner forum.
I like that this thread is taking me to those technical discussion memories and finding them!
I’ve used CHS 100 II quite a bit and I would recommend it to anyone who is pining over Panatomic-X. It has a lot to offer and definitely has classic film type traits.
I find Foma (100) and CHS 100 II as beautiful classic. Sadly the former has been having QC issues, the latter has intermittent availability and limited distribution. For dimensional and archival qualities I really like ESTAR/PET bases, and curiously in B&W roll films it is these smaller classic manufacturers coating film on them. Ilford and Kodak B&W are on Acetate.

Kodak has been making continuous R&D anyways, for changing components, and a big one is the AHU Cine films that recently were announced. For still films they have migrated the whole color film line to ESTAR base. Although the quote from Thomas Mooney is that B&W stays on Acetate due to antistatic properties, I wonder if that is also due to the engineering required for changing the base and honestly B&W surely does not have so much volume at Kodak so they keep the status quo.


Desirable for some but certainly not all. people are under the impression that film always looked weird, with colour crossovers and just general expired behaviours. But that simply isn't the case and it's a shame so many take on this view.
Agreed, despite being young I still have quite a lot of the old school philosophy of aiming for quality. But that there is a different, not so quality critical perception and appreciation of film is quite good and helping to finance the new films and experimental iterations. Not here, but specially there was some vitriol opinions about Harman Phoenix (II) in its thread!

It is curious as to how the consumer films are quoted as "older emulsion tech" aka Kodacolor VR 200 (plus) vs Gold vs Portra. Technology wise, there must be some costly components and processes that differentiate it. And that is a good question eg. if in B&W a tabular grain is cheaper to produce vs a cubical grain film; then in color if something like Portra is cheaper to produce than Gold than Kodacolor Plus.

Anyways, the market war of Kodak vs Fuji must have pushed a lot of improvements during its time; but generally it appears that film has been already very good quality wise since the late 90s/2000s. Digital then halted most of the big leaps, and then Digital itself is in the similar sufficiency and diminished returns nowadays. I recently renewed a camera body and essentially went for a model that has 2018-20 tech.
 

Alan Johnson

Subscriber
Joined
Nov 16, 2004
Messages
3,314
The differences in coating method between Efke and more modern methods are interesting but it appears that the main difference in the results between old and newer emulsions is the result of the change of the amounts of iodide in the emulsions:
 
OP
OP
Joined
Jan 7, 2020
Messages
44
Location
Melbourne, Australia
Format
Multi Format
This is super insightful. I've never shot efke but I remember hearing about them ceasing so to see what sort of equipment they were dealing with its really no wonder. Also shocking the methods in which they coated the emulsion and mixed everything. I totally believe that tech is pre WW2!

I've gone down a rabbit hole on coaters and how hard it would actually be to achieve acetate coating. I've found photos of a homemade single layer coater made from acrylic so it's certainly possible. Ultrasonic bubble removal also should be pretty simple. Finding a source for acetate material that's not crazy industrial quantities would be hard.

Also finding and refining emulsion formulas for a particular setup configuration would be somewhat hard.

I remember New55 apparently used a panatomic x emulsion so that's gotta be known out there somewhere. Certainly not a bad goal to make something of that nature
This would certainly explain why I've experienced static discharge through foma 100 emulsion before in 35 where as anything else has never been an issue for me.
I'd greatly think this would be the case. Acetate still lasts a very long time but it's off gassing after a few decades certainly isn't the nicest smell lol.
I do plan on using a chip chart and printing phoenix ii to ra4 and assessing the colour response. It's going to be terrible but a valuable test regardless.
 

Prest_400

Member
Joined
Jan 1, 2009
Messages
1,487
Location
Sweden
Format
Med. Format RF

I forgot Forte. They were set up in 1922 by Kodak and folded due to the digital revolution and by selling out to some real estate (IIRC) investors for the land. Probably they upgraded their manufacturing technology but don't know how far off or advanced they must have gone. I would assume whichever manufacturer that made color within the FSU sphere of influence was the most technically advanced (Orwo, Svema?).

But then there were also many more smaller and now forgotten film manufacturers. And more recently, plants owned by Kodak and Fuji.
Carestream's Colorado plant made Kodak's color paper and sadly shut down in 2023-24. Kodak Harrow, Fuji's facility in the Netherlands and so. Chinese Manufacturers (Shantou Era), etc etc.

Had a quick Google about Atomic-X, and it is just that they found the emulsion similar to Panatomic-X. It is interesting as to how simple or hard, specially referring to B&W, it might be to reproduce another film. Adox did it with CHSII, Fuji-Harman? did it with Acros II

About Foma, the 35mm films are coated on acetate. I find reasonable to believe that the material per se might come with some hard qualities/defects ie. PET as more static prone and light piping; but then some engineering to mitigate this.

Anyways, about the technology topic, would probably assume color to be more taxing in the manufacturing front. Though they well could make it with whatever coating technology they had in the 1930, 40, 50s and so up to the point that color took over the film market.
 

FredK

Member
Joined
Apr 23, 2013
Messages
26
Format
35mm

If I ever get around to it, I'll write the book which will answer all of these questions from the Kodak perspective. Each that you ask is very complex and would require many paragraphs to explain, as the film's technology changes are interwoven with changes to equipment, process changes, and of course, environmental requirments for health & safety.

As a brief example, all films emulsion coated in Building 38 became distinctly different than all of the other coating processes within Kodak worldwide. This was seen less with the still films vs. those in the motion picture family, but because the coating technology of Building 38 utilized far less water in each of the emulsion and dispersion layers, there was an immediate improvement in the film's widthwise and lengthwise uniformity. The thicker layers also reduced the movement of any particles within a layer such that the overall size of any imperfection was reduced by 3 to 5x in overall size. Those T-grained films saw a greater number of grains that would sit flat in each layer allowing better receptor sites, and the neccessary matching of gel types, viscosities, and simultaneous coating of more layers led to a fim structure that would be more consistent with less refraction leading to a cleaner appearance (improvement in sharpness).
 
Cookies are required to use this site. You must accept them to continue using the site. Learn more…