You'd want a white face to be placed in zone VI, not IV. Open up one stop from the zone V reading.
I think tkamiya has it correct now, just as eddie suggested.
eddie
Opening the aperture for exposure correction may help in explaining it to students, but it has the disadvantage over time corrections that it changes the image's depth of field. Hence, exposure corrections through shutter timing adjustments are preferred, because they do not alter the image.
Of course, when I taught, we had already gone over the relationship between shutter speed/f-stop before moving into tone placement. I should have mentioned that but, like I said, it was a long time ago...
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