Treat it like a chrome, especially if you're printing to RA4. It has huge contrast, so any scene with a lot of dynamic range (or big exposure errors) will result in blocked out regions.
Half a stop over doesn't really hurt but if you're scanning, you need to know how to correct the overexposure so that highlights aren't dead-looking.
While I'd say it is certainly a saturated film, it is nowhere near Velvia (Velveeta???). Velvia's colors are super-saturated, and it's also noticeably more of a green/blue bias whereas Ektar is somwhere between neutral and reds/yellows/oranges.
The one word of warning I have about Ektar is that it can emphasize any redness in a subject's face. Flushed cheeks or warm light can make faces look a bit red.
I shoot Ektar 100 in both 120 roll film and 4x5 sheets. Easy to develop at home with the c-41 press kit, easy to scan. I use a spot meter when doing LF, and sunny 16 when using my Yashica D. Very rarely, do I get a poor exposure using 100 iso.
Here are some Ektar 100 examples taken with my Yashica D
http://www.flickr.com/photos/83870148@N05/sets/72157630831836096/
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