For me, format choice is not as simple as saying you can crop a square into a rectangle, or a rectangle into a square. For me, I see differently when using either a 6X6 or a square. I end up with different images with different tools.
I have just recently started shooting a 645, and I have to say I really enjoy it. I had real apprehensions about the smaller negative and losing image quality, but am worrying less about that after doing some comparisons.
I recently shot an old run down farm building, with both a pentax 67, and a pentax 645. I used Acros, and a tripod for all the shots. With 11x14 black and white prints, any differences are imaginary I think.
I have found the pentax 645 to be a great travel camera. It, with a 55 and 150 lens can cover most of my requirements, fits in a small bag, and works much like a 35. One plus is that as my eyes have aged, I find it very difficult to focus some cameras; but not the pentax 645. The meter is accurate, lenses are first rate, and the system is cheap. What more could you want?
Downside- motor wind is not quiet, no interchangeable backs or finders, the controls take some getting used to.
I have never used a Mamiya or a Bronica, but I am sure they are just as good.
All that said, if I had to choose one camera for life it would be my rollei.....