I've used Diafine with IR820 quite a bit, but not so much for a speed increase as for a compensating effect. It keeps the highlights from blowing out so that, for instance, trees don't become unvariegated masses of white, and I think it generally makes the IR effects look more subtle. To me it makes for photos that are more interesting and less "gimmicky".
I don't rate IR820 as slow as some people do---typically ASA 3-6 with an 89B---but that's consistent across different developers, and I suspect it has to do with my local conditions and the fact that I generally shoot it at morning and evening (when IR levels compared to visible light are relatively high). If there's a true speed gain from Diafine over HC-110 or PC-TEA, it's pretty slight in my experience.
-NT