I have never shot a 4x5 camera but do have some experience with both E100G and Fuji FP100C in medium format. In terms of sensitivity and color palette, FP100C is similar but more saturated than E100G, actually quite close to E100VS. I'm not sure about deep shadows in FP100C and hope others can shed some light on that.
But my most important point: once in a lifetime occasions are hardly the right time for experiments. Regardless of what seasoned experts may write about E100G and FP100C45, you need the confidence on location that you can make this work. You get that confidence from running a couple of test shots with that camera in an area where you have fast turn around E6 labs (or can do home processing). Compare the scans (since that's your final output medium) to FP100C45 instant shots and judge for yourself, based on what's important to you.
Stack up all the resources you can muster for this event (test shots with notes, light meters, practice shots with this camera, equipment list, backup plan for broken equipment, ...), and you will have a high chance of succeeding, everything else would just be a gamble IMHO. Remember that
PPPPPPP.