If you can get the dye, and already have lots of film to experiment with, I would say go for it! Let us know how it works out.
I've thought of a project for my long term do list, to buy some blue sensitive X-ray film, which I believe has no sensitizing dyes added, and use Erythrosin B to make it orthochromtic. I know where to get the dye, and like you say, it might be fun. I can buy green sensitive X-ray film that is more or less orthochromatic already, but Erythrosin B should make it sensitive into the orange part of the spectrum, with a 'hole' in the blue-green, which I probably don't need anyway.