One way to get this might be with a double exposure - set the camera on a tripod, put a red filter on the lens, and mid-day or late morning, shoot the barn. The ratio of the brightness on the side of the barn to the sky should be less than looking into the setting sun. The red filter will help to darken the sky and hopefully not darken the roof/side of the barn too much. Focus on getting the exposure on the roof right. Now go and read a book, and wait for nightfall Once there is little ambient light and the dominant light is from the 'floodlights' do a second exposure, this time looking at the light on the side of the barn, where it is lit by the floodlights, and underexpose by a bit. If it all comes out right, the blue sky comes out dark because of the red filter on the first exposure, and is dark in the second exposure. The mid-day illumination of the side of the barn is augmented by the lights, giving it the appearance of being late afternoon, the roof exposure should have been set in the first exposure.