Marcus -
I've done both. My experience is:
- spray mounting works well with RC paper, and perhaps also with single-weight FB paper. But there is a problem with double-weight FB paper. Over time, FB paper wants to curl, and the force exerted by double-weight paper as it curls is enough to cause the edges of the print to lift away from the mount.
- heat-triggered paper does an excellent job of attaching prints to mounts when used with a mounting press. My experience in trying to use it with an ordinary flat iron was unsuccessful. An iron will certainly get hot enough to trigger the adhesive. The problem that I had was in getting it to adhere uniformly across the entire print. I found the lack of uniform heating resulted in bubbles that really detracted from the appearance.
There is a third option - the 3M pressure-sensitive adhesive sheets. My limited experience with these is more positive. However, I believe that the materials are also more expensive.
By the way, all three approaches are controversial. There are those who will argue that processes like these are not reversible, and therefore aren't archival.