I tried splitting it once. The powder that was left, when mixed, turned in to a brown, sticky and lumpy, soup and the chems didn't dissolve completely. Totally unusable. I had been storing the powders in their bags and then inside an air-tight jar but even the moisture that was left in the jar was enough to ruin what was left of the kit in about one month. It was my first kit and I had heard all the horror stories on how fast C-41 chems go off and was concerned about the longevity of the mixed liquids. Later, in my own experience, I have kept and re-used mixed C-41 press kit liquids six months after mixing, with no ill effects (until exhaustion around 15 processed rolls).
So the short of the long is: mix up the whole kit at once. Store in brown air-tight glass bottles that are as full as possible and you are good for 15 rolls or the equivalent in sheet film within six months (at least!).