While I agree that Rodinal mixed does not last, in most parts of the world with running water, air is added to the water to make it flow through pipes more easily. The result is more oxygen and bubbles in water than is normal; if using tap water, I generally either boil it and let it cool (removes oxygen bubbles) or I let it sit for more than 24 hours to get the air out prior to mixing. The obvious alternative is using distilled but that's a different discussion. The result is a sightly longer lasting working mixture but only by a couple of hours. I do find less spots on my negatives and more control from agitation.