Hey Joe,
I use Diafine for almost all my film processing, and like it a lot. It works expecially well with Tri-x, giving it an e.i. of 1250, and with Fomapan 100 (with an e.i. of 100). With Tri-x, it is better suited for contrasty scences (indoors, night shots, but not sunlight). Fomapan seems to work great with sunlight (I might print an example in the next few days and post it).
I have used Diafine with a surplus (defective) lot of Macophot UP100+, which is the same emulsion of efke 100. Bearing in mind that this was a defective lot (some say the e.i. was closer to 50) I did not like it much in Diafine. I shot A LOT of it at e.i. 200, which gave me WONDERFUL tones. The problem was that the negs were really thin, and I had to print at grade 4 & 5.
Diafine is not very time sensitive - all films develop in 3 minutes bath A and 3 minutes bath B; temperatures don't mean much either - I keep mine close to 68-72 just for peace of mind (I also develop for 4 minutes in each bath just so if I lose count of the minutes no harm is done).
I would suggest buying a bit of it and trying it out. This is a low agitation developer, so I would simply turn the rotary processor off and agitate 3 slow inversions each minute by hand. Also, the stuff lasts forever, so its extremely cost effective (its cheap to start, too!).
Anyway, take a look at my APUG gallery for lots of examples of the efke-ish emulsion in Diafine (the 6x6 shots), and tri-x (the 35mm shots).
hope this helps,
André