Wait -- you're using Xtol Stock? Because you said you're wasting chemistry.
Not one shot, but stock, it doesn't matter how many times you fill the tank it's how many rolls you do. Basically, you get 15 rolls per liter, and you adjust times 15% after the first 5, then 15% more after 10, then at 15 rolls developed you discard and move on to the next liter.
So doing it one at a time is not wasteful. Pour in as much as you like, pour it back into the bottle of working solution, and mark 1 roll wherever it is you keep count. It's very economical and you do not have to be precise about the amount in the dev tank.
Anyway, If you mean one shot, sorry for all the words if I'm wrong, but to your initial question times are the same whether you're developing one roll or multiple rolls in the tank at the same time.