Hi,
IME the sharpest prints will come when you do no resampling, and change only ppi to resize the image. This does not remove or add pixels to the file in order to change it's size. The less you tinker with the locations and numbers of the pixels of the original file, the better.
14 Mpix not resampled will give you a decent-sized print even in inkjet prints made at a high dpi on standard inkjet paper. 360 dpi gives you a 9x12 inch image. If you go down to 240, which is perfectly respectable for an inkjet IME, you get a 13.5x18 inch print. (That is HUGE, considering that it is coming from a subminiature format sensor that has 1/3 the area of a Minox frame.) Canvas surface is less demanding on dpi, so you can go quite large without even having to resample. Ideally you use 240 or 360, but you can go as low as 100 and it will still look "good" on canvas. That would give you a 32x43 inch print. Factor in that most people will view a print that size from relatively far away, and it will look even "better than good."
If you do have the need to upsample the image, there are programs that are better at it than Photoshop, such as Genuine Fractals. It is probably a worthy investment if you will need to upsample frequently.
The only thing I have considered in my response thus far is image size. But there are other factors that are far more important. The technical soundness of the image itself is key. This has to do with technique and the lens, among other things. Just because you can easily make a big print without pixelization does not necessarily mean that it will be sharp.