hello,
as you noted D-94A is for Kodaks reversal process, and if I understand you right you'd like to develop it as negative in XTOL instead.
That should give very good results for scanning or printing. I never processed Wittner PXR in XTOL, but I did with Kodak Plus-X 7265 and Tri-X 7266.
I've heard somewhere that Wittner PXR is Efke 50, and developing times for that film are listed as 8min @20C stock solution and 10min for 1+1, which sounds about right.
So I would use a test strip with those times, and since it's most likely out of date film stock, I'd give it half a stop more exposure.
hope that helps