bloke on reddit said:I looked around for a solution for a while until I found an alternate formula called "blue sheet" (since it colours the paper slightly blue instead of yellow before development) that uses potassium ferrocyanide instead of potassium ferricyanide. It was apparently used quite a lot in commercial architectural blueprints in the early 20th century, but there is very little information about it now and it seems barely anyone uses it. Which is weird, since it blows regular cyanotypes out of the water. It's a lot more sensitive and has a much better tonality. You don't need to completely overexpose the image like with the regular stuff. The only drawback is that it's not a print-out process, so you can't see how your image is coming along, and it takes an extra oxidizing step to get the final image, but it's totally worth it.
'm a little skeptical of any difference in ferro vs. ferri cyanide, other than the name, but I'm no chemist. I wonder if it's just a matter of coating the paper with the ferricyanide, exposing, and then developing under a bath of ferric ammonium citrate.
WHat do you mean "skeptical of any difference" ? They're different compounds.
As for coating, ferricyanide is not the light sensitive part here - that's the Ferric ammonium citrate.
You can certainly coat paper with Ferric ammonium citrate, expose it, and then "develop" with ferricyanide (I've done it myself, and it is a little faster and a little less contrasty), but it is not clear that this is what the author is referring to.
It only works with this particular formular regardless, so unless there are other highly sensitised (eg not printing out) alt processes i can't see it working too well.
Why not use an actual enlarging lens (el nikkors pass UV) and UV LEDs too?
I don't mind digital negatives, but I like the idea of an enlarger. I've done both digital negatives and interpositives and enlargements onto large sheets of xray film. In either case there's a much bigger investment in time and money than enlarging the negative directly as a cyanotype. This new process won't be the game changer that digital negatives were, but I like having an alternative. Cyanotype enlargements open up the possibility of long exposure in-camera cyanotype negatives as well.
After doing some more digging on the chemicals involved, I wonder, how does this "blue sheet" process differ from cyanotype rex?
The author also posted about it in the darkroom subreddit, which I now moderate. A few possible refinements to the design are discussed there. He later posted his first images from the contraption.
Regarding Reddit being a "horrible place", I would agree - as long as we also agree that "the internet" is a horrible place. Subreddits on particular subject are more akin to forums on particular subjects, like this one. People with a common interest hanging out and discussing that particular subject. Reddit also probably has a younger-skewed demographic, though one should not paint entirely with broad brushes if one wants a good picture. (I'm 56).
If we want companies, like Ilford, to continue to produce traditional photographic paper (etc.) then they will need the dollars of the younger generations. Fostering appreciation for film and darkroom work in places where they congregate (like Reddit) is one to help that happen.
PS... Discussion of Alternative Processes is welcome in r/Darkroom.
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