Here is a list of the residual between the fit and the data for the four parameter fit I showed earlier.
RESIDUALS
-0.00814735474025491
0.00443299720689611
-0.00495683903640237
0.00927281290335008
0.0186755876170858
-0.0117224326914512
-0.0187317246975552
-0.00515886458521414
-0.00172260138239366
0.0141963929648516
0.0225380760765277
-0.00312415700747659
0.00257906197888336
0.0359646349921837
-0.0544397383232357
-0.0420528610374982
-0.00949162093982636
0.0151039044630277
-0.0271638726211845
0.00310327956330925
-0.00466891187437768
0.00313234397646411
0.0109405486984975
0.057643304979889
0.0535096713490784
The maximum deviation is about 1/5 stop, which is not a lot.
For the six parameter model the residuals are as follows.
OTHER_RESIDUAL
-0.00865538809797933
0.00429587801755249
-0.00471582502816537
0.00982849469006986
0.0192905480795434
-0.0113471586589236
-0.0188551747281989
-0.00592387433963665
-0.00290941838266201
0.0128966866227697
0.0215282306281418
-0.00353167589170789
0.00302865642946382
0.0375730821164881
-0.0516656584672155
-0.0380676412445947
-0.00432637463678009
0.021395202826574
-0.0202538528298055
0.00981449003702384
-0.000141232715030082
0.00223204673597954
-0.00124480933729565
0.0172293681725331
-0.0147493797907858
The maximum residual between the fit and the data points approximately 1/8 stop.
A fifth order polynomial gave a maximum residual of about 1/7 stop, which is close but not quite as close as the six parameter equation. The visual comparison between the fifth order polynomial fit and the six parameter fit is pretty comparable (data not shown).
As a point of comparison, a fifth order polynomial has six degrees of freedom (six adjustable parameters), which is the same number of degrees of freedom as my six parameter equation.
Based on this, it looks like there is a not a lot to choose between the polynomial fit and the six parameter equation. Nevertheless, I tend to prefer my equation because it is constrained to have the right qualitative shape, whereas the polynomial is not.
Spline functions are, of course, another story altogether.